This stone is generally found among the bituminous schistus, or black argillaceous strata, either in separate ma.s.ses of various shapes and sizes, or forming of itself strata which are more or less continuous in their direction among the schistous or argillaceous beds.

This mineral contains, in general, from 40 to 50 _per cent._ of iron, and it loses near one third of its weight in calcination. Before calcination it is of a grey colour, is not penetrable by water, and takes a polish. In this state, therefore, it is perfectly solid; but being calcined, it becomes red, porous, and tender.

The fact to be proved with regard to these iron-stones is this, That they have acquired their solid state from fusion, and not in concreting from any aqueous solution.

To abridge this disquisition, no argument is to be taken from contingent circ.u.mstances, (which, however, are often found here as well as in the case of marbles); such only are to be employed as are general to the subject, and arise necessarily from the nature of the operation.

It will be proper to describe a species of these stones, which is remarkably regular in its form. It is that found at Aberlady, in East Lothian.

The form of these iron-stones is that of an oblate or much compressed sphere, and the size from two or three inches diameter to more than a foot. In the circular or horizontal section, they present the most elegant septarium[9]; and, from the examination of this particular structure, the following conclusions may be drawn.

_First_, That, the septa have been formed by the uniform contraction of the internal parts of the stone, the volume of the central parts diminishing more than that of the circ.u.mference; by this means, the separations of the stone diminish, in a progression from the center towards the circ.u.mference.

_2d_, That there are only two ways in which the septa must have received the spar or spatthose ore with which they are filled, more or less, either, _first_ By insinuation into the cavity of the septa after these were formed; or, _2dly_, By separation from the substance of the stone, at the same time that the septa were forming.

[Note 9: Plate I.]

Were the first supposition true, appearances would be observable, showing that the sparry substance had been admitted, either through the porous structure of the stone, or through proper apertures communicating from without. Now, if either one or other of these had been the case, and that the stone had been consolidated from no other cause than concretion from a dissolved state, that particular structure of the stone, by means of which the spar had been admitted, must appear at present upon an accurate examination.

This, however, is not the case, and we may rest the argument here. The septa reach not the circ.u.mference; the surface of the stone is solid and uniform in every part; and there is not any appearance of the spar in the argillaceous bed around the stone.

It, therefore, necessarily follows, that the contraction of the iron-stone, in order to form septa, and the filling of these cavities with spar, had proceeded _pari pa.s.su_; and that this operation must have been brought about by means of fusion, or by congelation from a state of simple fluidity and expansion.

It is only further to be observed, that all the arguments which have been already employed, concerning mineral concretions from a simply fluid state, or that of fusion, here take place. I have septaria of this kind, in which, besides pyrites, iron-ore, calcareous spar, and another that is ferruginous and compound, there is contained siliceous crystals; a case which is not so common. I have them also attended with circ.u.mstances of concretion and crystallization, which, besides being extremely rare, are equally curious and interesting.

There is one fact more which is well worth our attention, being one of those which are so general in the mineral regions. It is the crystallizations which are found in close cavities of the most solid bodies.

Nothing is more common than this appearance. Cavities are every where found closely lined with crystallizations, of every different substance which may be supposed in those places. These concretions are well known to naturalists, and form part of the beautiful specimens which are preserved in the cabinets of collectors, and which the German mineralists have termed _Drusen_. I shall only particularise one species, which may be described upon principle, and therefore may be a proper subject on which to reason, for ascertaining the order of production in certain bodies. This body, which we are now to examine, is of the agate species.

We have now been considering the means employed by nature in consolidating strata which were originally of an open structure; but in perfectly solid strata we find bodies of agate, which have evidently been formed in that place where they now are found. This fact, however, is not still that of which we are now particularly to inquire; for this, of which we are to treat, concerns only a cavity within this agate; now, whatever may have been the origin of the agate itself, we are to show, from what appears within its cavity, that the crystallizations which are found in this place had arisen from a simply fluid state, and not from that of any manner of solution.

The agates now in question are those of the coated kind, so frequent in this country, called pebbles. Many of these are filled with a siliceous crystallization, which evidently proceeds from the circ.u.mference towards the centre. Many of them, again, are hollow. Those cavities are variously lined with crystallized substances; and these are the object of the present examination.

But before describing what is found within, it is necessary to attend to this particular circ.u.mstance, that the cavity is perfectly inclosed with many solid coats, impervious to air or water, but particularly with the external cortical part, which is extremely hard, takes the highest polish, and is of the most perfect solidity, admitting the pa.s.sage of nothing but light and heat.

Within these cavities, we find, _1st_, The coat of crystals with which this cavity is always lined; and this is general to all substances concreting, in similar circ.u.mstances, from a state of fusion; for when thus at liberty they naturally crystallise. _2dly_, We have frequently a subsequent crystallization, resting on the first, and more or less immersed in it. _3dly_, There is also sometimes a third crystallization, superinc.u.mbent on the second, in like manner as the second was on the first. I shall mention some particulars.

I have one specimen, in which the primary crystals are siliceous, the secondary thin foliaceous crystals of deep red but transparent iron-ore, forming elegant figures, that have the form of roses. The tertiary crystallization is a frosting of small siliceous crystals upon the edges of the foliaceous crystals.

In other specimens, there is first a lining of colourless siliceous crystals, then another lining of amethystine crystals, and sometimes within that, fuliginous crystals. Upon these fuliginous and amethystine crystals are many sphericles or hemispheres of red compact iron-ore, like haemat.i.tes.

In others, again, the primary crystals are siliceous, and the secondary calcareous. Of this kind, I have one which has, upon the calcareous crystals, beautiful transparent siliceous crystals, and iron sphericles both upon all these crystals, and within them.

_Lastly_, I have an agate formed of various red and white coats, and beautifully figured. The cavity within the coated part of the pebble is filled up without vacuity, first, with colourless siliceous crystals; secondly, with fuliginous crystals; and, lastly, with white or colourless calcareous spar. But between the spar and crystals there are many sphericles, seemingly of iron, half sunk into each of these two different substances.

From these facts, I may now be allowed to draw the following conclusions:

1_st_, That concretion had proceeded from the surface of the agate body inwards. This necessarily follows from the nature of those figured bodies, the figures of the external coats always determining the shape of those within, and never, contrarily, those within affecting those without.

2_dly_, That when the agate was formed, the cavity then contained every thing which now is found within it, and nothing more.

3_dly_, That the contained substances must have been in a fluid state, in order to their crystallizing.

_Lastly_, That as this fluid state had not been the effect of solution in a menstruum, it must have been fluidity from heat and fusion.

Let us now make one general observation and argument with regard to the formation of those various coated, concreted, crystallized, and configured bodies. Were the crystallization and configuration found to proceed from a central body, and to be directed from that centre outwards, then, without inquiring into collateral appearances, and other proofs with regard to the natural concretion of those substances, we might suppose that these concretions might have proceeded from that central body gradually by accretion, and that the concreting and crystallizing substances might have been supplied from a fluid which had before retained the concreting substance in solution; in like manner as the crystallizations of sugar, which are formed in the solution of that saccharine substance, and are termed candies, are formed upon the threads which are extended in the crystallizing vessel for that purpose.

But if, on the contrary, we are to consider those mineral bodies as spheres of alternate coats, composed of agate, crystal, spars, etc.; and if all those crystallizations have their _bases_ upon the uncrystallized coat which is immediately external to it, and their _apices_ turned inwards into the next internal solid coat, it is not possible to conceive that a structure of this kind could have been formed in any manner from a solution. But this last manner is the way without exception in which those mineral bodies are found; therefore we are to conclude, that the concretion of those bodies had proceeded immediately from a state of fusion or simple fluidity.

In granite these cavities are commonly lined with the crystal corresponding to the const.i.tuent substances of the stone, viz. quartz, feld-spar, and mica or talk. M. de Saussure, (Voyages dans les Alpes, tom. ii. --722.), says, "On trouve frequemment des amas considerables de spath calcaire, crystallise dans les grottes ou se forme le crystal de roche; quoique ces grottes soient renfermees dans le coeur des montagnes d'un granit vif, & qu'on ne voie aucun roc calcaire au dessus de ces montagnes."

So accurate an observer, and so complete a naturalist, must have observed how the extraneous substance had been introduced into this cavity, had they not been formed together the cavity and the calcareous crystals. That M. de Saussure perceived no means for that introduction, will appear from what immediately follows in that paragraph. "Ces rocs auroient-ils ete detruits, ou bien ce spath n'est il que le produit d'une secretion des parties calcaires que l'on fait etres dispersees entre les divers elemens du granit?"

Had M. de Saussure allowed himself to suppose all those substances in fusion, of which there cannot be a doubt, he would soon have resolved both this difficulty, and also that of finding molybdena crystallized along with feld-spar, in a cavity of this kind. --718.

To this argument, taken from the close cavities in our agates, I am now to add another demonstration. It is the case of the calcedony agate, containing a body of calcareous spar; here it is to be shown, that, while the calcareous body was altogether inclosed within the calcedony nodular body, these two substances had been perfectly soft, and had mutually affected each others shape, in concreting from a fluid state.

In order to see this, we are to consider that both those substances have specific shapes in which they concrete from the third state; the sparry structure of the one is well known; the spherical or mammelated crystallization of the calcedony, is no less conspicuous; this last is, in the present case, spherical figures, which are some of them hemispheres, or even more. The figures which we have now in contemplation are so distinctly different as cannot be mistaken; the one is a rhombic figure bounded by planes; the other is a most perfect spherical form; and both these are specific figures, belonging respectively to the crystallization of those two substances.

The argument now to be employed for proving that those two bodies had concreted from the fluid state of fusion, and not from any manner of solution, is this: That, were the one of those bodies to be found impressing the other with its specific figure, we must conclude that the impressing body had concreted or crystallized while the impressed body was in a soft or fluid state; and that, if they are both found mutually impressing and impressed by each other, they must have both been in the fluid and concreting state together. Now the fact is, that the calcareous body is perfectly inclosed within the solid calcedony, and that they are mutually impressed by each others specific figure, the sparry structure of the calcareous body impressing the calcedony with its type of planes and angles, at the same time that, in other parts, the spherical figures of the calcedony enter the solid body of the spar, and thus impress their mammelated figures into that part which is contiguous. It is therefore inconceivable, that these appearances could have been produced in any other manner than by those two bodies concreting from a simply fluid state.

There are in jaspers and agates many other appearances, from whence the fusion of those substances may be concluded with great certainty and precision; but it is hoped, that what has been now given may suffice for establishing that proposition without any doubt.

It must not be here objected, That there are frequently found siliceous crystals and amethysts containing water; and that it is impossible to confine water even in melted gla.s.s. It is true, that here, at the surface of the earth, melted gla.s.s cannot, in ordinary circ.u.mstances, be made to receive and inclose condensed water; but let us only suppose a sufficient degree of compression in the body of melted gla.s.s, and we can easily imagine it to receive and confine water as well as any other substance. But if, even in our operations, water, by means of compression, may be made to endure the heat of red hot iron without being converted into vapour, what may not the power of nature be able to perform? The place of mineral operations is not on the surface of the earth; and we are not to limit nature with our imbecility, or estimate the powers of nature by the measure of our own.[10]

[Note 10: This is so material a principle in the theory of consolidating the strata of the earth by the fusion of mineral substances, that I beg the particular attention of the reader to that subject. The effect of compression upon compound substances, submitted to increased degrees of heat, is not a matter of supposition, it is an established principle in natural philosophy. This, like every other physical principle, is founded upon matter of fact or experience; we find, that many compound substances may with heat be easily changed, by having their more volatile parts separated when under a small compression; but these substances are preserved without change when sufficiently compressed.

Our experiments of this kind are necessarily extremely limited; they are not, however, for that reason, the less conclusive. The effects of increasing degrees of heat are certainly prevented by increasing degrees of compression; but the rate at which the different effects of those powers proceed, or the measure of those different degrees of increase that may be made without changing the const.i.tution of the compound substance, are not known; nor is there any limit to be set to that operation, so far as we know. Consequently, it is a physical principle, That the evaporation of volatile substances by heat, or the reparation of them from a compound substance, consequently the effect of fire in changing that compound substance, may be absolutely prevented by means of compression.

It now remains to be considered, how far there is reason to conclude that there had been sufficient degrees of compression in the mineral regions, for the purpose of melting the various substances with which we find strata consolidated, without changing the chemical const.i.tution of those compound substances.

Had I, in reasoning _a priori_, a.s.serted, That all mineral bodies might have been melted without change, when under sufficient compression, there might have arisen, in the minds of reasoning men, some doubt with regard to the certainty of that proposition, however probable it were to be esteemed: But when, in reasoning _a posteriori_, it is found that all mineral bodies have been actually melted, then, all that is required to establish the proposition on which I have founded my theory, is to see that there must have been immense degrees of compression upon the subjects in question; for we neither know the degree of heat which had been employed, nor that of compression by which the effect of the heat must have been modified.

Now, in order to see that there had been immense compression, we have but to consider that the formation of the strata, which are to be consolidated, was at the bottom of the ocean, and that this place is to us unfathomable. If it be farther necessary to show that it had been at such unfathomable depth strata were consolidated, it will be sufficient to observe, it is not upon the surface of the earth, or above the level of the sea, that this mineral operation can take place; for, it is there that those consolidated bodies are redissolved, or necessarily going into decay, which is the opposite to that operation which we are now inquiring after; therefore, if they were consolidated in any other place than at the bottom of the sea, it must have been between that place of their formation and the surface of the sea; but that is a supposition which we have not any reason to make; therefore, we must conclude that it was at the bottom of the ocean those stratified bodies had been consolidated.]

To conclude this long chemico-mineral disquisition, I have specimens in which the mixture of calcareous, siliceous, and metallic substances, in almost every species of concretion which is to be found in mineral bodies, may be observed, and in which there is exhibited, in miniature, almost every species of mineral transaction, which, in nature, is found upon a scale of grandeur and magnificence. They are nodules contained in the whin-stone, porphyry, or basaltes of the Calton-hill, by Edinburgh; a body which is to be afterwards examined, when it will be found to have flowed, and to have been in fusion, by the operation of subterraneous heat.

This evidence, though most conclusive with regard to the application of subterraneous heat, as the means employed in bringing into fusion all the different substances with which strata may be found consolidated, is not directly a proof that strata had been consolidated by the fusion of their proper substance. It was necessary to see the general nature of the evidence, for the universal application of subterraneous heat, in the fusion of every kind of mineral body. Now, that this has been done, we may give examples of strata consolidated without the introduction of foreign matter, merely by the softening or fusion of their own materials.

For this purpose, we may consider two different species of strata, such as are perfectly simple in their nature, of the most distinct substances, and whose origin is perfectly understood, consequently, whose subsequent changes may be reasoned upon with certainty and clearness. These are the siliceous and calcareous strata; and these are the two prevailing substances of the globe, all the rest being, in comparison of these, as nothing; for unless it be the bituminous or coal strata, there is hardly any other which does not necessarily contain more or less of one or other of these two substances. If, therefore, it can be shown, that both of those two general strata have been consolidated by the simple fusion of their substance, no _desideratum_ or doubt will remain, with regard to the nature of that operation which has been transacted at great depths of the earth, places to which all access is denied to mortal eyes.

We are now to prove, _first_, That those strata have been consolidated by simple fusion; and, _2dly_, That this operation is universal, in relation to the strata of the earth, as having produced the various degrees of solidity or hardness in these bodies.

I shall first remark, that a fortuitous collection of hard bodies, such as gravel and sand, can only touch in points, and cannot, while in that hard state, be made to correspond so precisely to each others shape as to consolidate the ma.s.s. But if these hard bodies should be softened in their substance, or brought into a certain degree of fusion, they might be adapted mutually to each other, and thus consolidate the open structure of the ma.s.s. Therefore, to prove the present point, we have but to exhibit specimens of siliceous and calcareous strata which have been evidently consolidated in this manner.

Of the first kind, great varieties occur in this country. It is, therefore, needless to describe these particularly. They are the consolidated strata of gravel and sand, often containing abundance of feld-spar, and thus graduating into granite; a body, in this respect, perfectly similar to the more regular strata which we now examine.

The second kind, again, are not so common in this country, unless we consider the sh.e.l.ls and coralline bodies in our lime-stones, as exhibiting the same example, which indeed they do. But I have a specimen of marble from Spain, which may be described, and which will afford the most satisfactory evidence of the fact in question.

This Spanish marble may be considered as a species of pudding-stone, being formed of calcareous gravel; a species of marble which, from Mr Bowles' Natural History, appears to be very common in Spain. The gravel of which this marble is composed, consists of fragments of other marbles of different kinds. Among these, are different species of _oolites_ marble, some sh.e.l.l marbles, and some composed of a chalky substance, or of undistinguishable parts. But it appears, that all these different marbles had been consolidated or made hard, then broken into fragments, rolled and worn by attrition, and thus collected together, along with some sand or small siliceous bodies, into one ma.s.s. Lastly, This compound body is consolidated in such a manner as to give the most distinct evidence, that this had been executed by the operation of heat or simple fusion.