Our knowledge is extremely limited with regard to the effects of heat in bodies, while acting under different conditions, and in various degrees.

But though our knowledge in these respects is limited, our judgment with regard to the efficacy of this power of heat is in its nature positive, and contains not any thing that is doubtful or uncertain. All mankind, who have the opportunity, know that the hard substance of ice is by heat converted into water, wherein no hardness remains; and the profound philosophy of Dr Black, in relation to the subject of _latent heat_, as that of Sir Isaac Newton, in relation to the weight of bodies, is not necessary to convince the world that in the one case ice will melt, and in the other, that heavy bodies will move when unsupported.

But though, in the abstract doctrine of _latent heat_, the ingenuity of man has discovered a certain measure for the quant.i.ty of those commutable effects which are perceived; and though this be a progress of science far above the apprehension of the vulgar, yet still, that solid bodies are changed into fluids, by the power of heat, is the same unalterable judgment, which the savage forms as well as the philosopher.

Here, therefore, are evident effects, which mankind in general attribute to the power of heat; and it is from those known effects that we are to investigate subterraneous fire, or to generalise the power of heat, as acting in the interior parts, as well as on the surface of this earth.

If, indeed, there were any other cause for fluidity besides the operation of fire or the power of heat, in that case the most evident proof, with regard to the flowing, or former fluidity, of mineral bodies, would draw to no conclusion in proving the existence of mineral fire; but when we have not the smallest reason for conjecturing any other cause, or the least doubt with regard to that which, in the doctrine of latent heat, has been properly investigated, the proofs which we shall bring, of fusion in all the minerals of this earth, must be held as proofs of mineral fire, in like manner as the proof of subterraneous fire would necessarily imply mineral fusion as its natural effect.

Thus we have, in our physical investigation, several points in view.

First, from the present state of things, to infer a former state of fusion among mineral bodies. Secondly, from that former fusion, to infer the actual existence of mineral fire in the system of the earth. And, lastly, from the acknowledged fact of subterraneous fire as a cause, to reason with regard to the effects of that power in mineral bodies.

But besides the power or effect of subterraneous heat in bodies which are unorganised, and without system, in the construction of their different parts, we have to investigate the proper purpose of this great agent in the system of this world, which may be considered as a species of organised body. Here, therefore, final causes are to be brought into view, as well as those which are efficient. Now, in a subject involved with so much obscurity, as must be for us the internal regions of the globe, the consideration of efficient and final causes may contribute mutually to each others evidence, when separately the investigation of either might be thought unsatisfactory or insufficient.

So far it seemed necessary to premise with regard to the great mineral power which we are to employ as an agent in the system of this earth; and it may be now observed, that it is in the proper relation of this power of heat and the fluidity or softness of bodies, as cause and effect, that we are to find a physical principle or argument for detecting those false theories of the earth that have been only imagined, and not properly founded on fact or observation. It is also by means of this principle, that we shall be enabled to form a true theory of the mineral region, in generalising particular effects to a common cause.

Let us now proceed in endeavouring to decide this important question, viz. By what active principle is it, that the present state of things, which we observe in the strata of the earth, a state so very different from that in which those bodies had been formed originally, has been brought about?

Two causes have been now proposed for the consolidating of loose materials which had been in an incoherent state; these are, on the one hand, fire; or, on the other, water, as the means of bringing about that event. We are, therefore, to consider well, what may be the consequences of consolidation by the one or other of those agents; and what may be the respective powers of those agents with respect to this operation.

If we are not informed in this branch of science, we may gaze without instruction upon the most convincing proofs of what we want to attain.

If our knowledge is imperfect, we may form erroneous principles, and deceive ourselves in reasoning with regard to those works of nature, which are wisely calculated for our instruction.

The strata, formed at the bottom of the sea, are to be considered as having been consolidated, either by aqueous solution and crystallization, or by the effect of heat and fusion. If it is in the first of these two ways that the solid strata of the globe have attained to their present state, there will be a certain uniformity observable in the effects; and there will be general laws, by which this operation must have been conducted. Therefore, knowing those general laws, and making just observations with regard to the natural appearances of those consolidated ma.s.ses, a philosopher, in his closet, should be able to determine, what may, and what may not have been transacted in the bowels of the earth, or below the bottom of the ocean.

Let us now endeavour to ascertain what may have been the power of water, acting under fixed circ.u.mstances, operating upon known substances, and conducting to a certain end.

The action of water upon all different substances is an operation with which we are familiar. We have it in our power to apply water in different degrees of heat for the solution of bodies, and under various degrees of compression; consequently, there is no reason to conclude any thing mysterious in the operations of the globe, which are to be performed by means of water, unless an immense compressing power should alter the nature of those operations. But compression alters the relation of evaporation only with regard to heat, or it changes the degree of heat which water may be made to sustain; consequently, we are to look for no occult quality in water acting upon bodies at the bottom of the deepest ocean, more than what can be observed in experiments which we have it in our power to try.

With regard again to the effect of time: Though the continuance of time may do much in those operations which are extremely slow, where no change, to our observation, had appeared to take place, yet, where it is not in the nature of things to produce the change in question, the unlimited course of time would be no more effectual, than the moment by which we measure events in our observations.

Water being the general medium in which bodies collected at the bottom of the sea are always contained, if those ma.s.ses of collected matter are to be consolidated by solution, it must be by the dissolution of those bodies in that water as a menstruum, and by the concretion or crystallization of this dissolved matter, that the s.p.a.ces, first occupied by water in those ma.s.ses, are afterwards to be filled with a hard and solid substance; but without some other power, by which the water contained in those cavities and endless labyrinths of the strata, should be separated in proportion as it had performed its task, it is inconceivable how those ma.s.ses, however changed from the state of their first subsidence, should be absolutely consolidated, without any visible or fluid water in their composition.

Besides this difficulty of having the water separated from the porous ma.s.ses which are to be consolidated, there is another with which, upon this supposition, we have to struggle. This is, From whence should come the matter with which the numberless cavities in those ma.s.ses are to be filled?

The water in the cavities and interstices of those bodies composing strata, must be in a stagnating state; consequently, it can only act upon the surfaces of those cavities which are to be filled up. But with what are they to be filled? Not with water; they are full of that already: Not with the substance of the bodies which contain that water; this would be only to make one cavity in order to fill up another.

If, therefore, the cavities of the strata are to be filled with solid matter, by means of water, there must be made to pa.s.s through those porous ma.s.ses, water impregnated with some other substances in a dissolved state; and the aqueous menstruum must be made to separate from the dissolved substance, and to deposit the same in those cavities through which the solution moves.

By such a supposition as this, we might perhaps explain a partial consolidation of those strata; but this is a supposition, of which the case under consideration does not admit; for in the present case, which is that of materials acc.u.mulated at the bottom of the ocean, there is not proper means for separating the dissolved matter from the water included in those enormous ma.s.ses; nor are there any means by which a circulation in those ma.s.ses may be formed. In this case, therefore, where the means are not naturally in the supposition, a philosopher, who is to explain the phenomenon by the natural operation of water in this situation, must not have recourse to another agent, still more powerful, to a.s.sist his supposition which cannot be admitted.

Thus, it will appear, that, to consolidate strata formed at the bottom of the sea, in the manner now considered, operations are required unnatural to this place; consequently, not to be supposed, in order to support a hypothesis.

But now, instead of inquiring how far water may be supposed instrumental in the consolidation of strata which were originally of a loose texture, we are to consider how far there may be appearances in those consolidated bodies, by which it might be concluded, whether or not the present state of their consolidation has been actually brought about by means of that agent.

If water had been the menstruum by which the consolidating matter was introduced into the interstices of strata, ma.s.ses of those bodies could only be found consolidated with such substances as water is capable of dissolving; and these substances would be found only in such a state as the simple separation of the solvent water might produce.

In this case, the consolidation of strata would be extremely limited; for we cannot allow more power to water than we find it has in nature; nor are we to imagine to ourselves unlimited powers in bodies, on purpose to explain those appearances by which we should be made to know the powers of nature. Let us, therefore, attend, with every possible circ.u.mspection, to the appearances of those bodies, by means of which we are to investigate the principles of mineralogy, and know the laws of nature.

The question now before us concerns the consolidating substances of strata. Are these such as will correspond to the dissolving power of water, and to the state in which these substances might be left by the separation of their menstruum? No; far, far from this supposition is the conclusion that necessarily follows from natural appearances.

We have strata consolidated by calcareous spar, a thing perfectly distinguishable from the stalactical concretion of calcareous earth, in consequence of aqueous solution. We have strata made solid by the formation of fluor, a substance not soluble, so far as we know, by water. We have strata consolidated with sulphureous and bituminous substances, which do not correspond to the solution of water. We have strata consolidated with siliceous matter, in a state different from that under which it has been observed, on certain occasions, to be deposited by water. We have strata consolidated by feld-spar, a substance insoluble in water. We have strata consolidated by almost all the various metallic substances, with their almost endless mixtures and sulphureous compositions; that is to say, we find, perhaps, every different substance introduced into the interstices of strata which had been formed by subsidence at the bottom of the sea.

If it is by means of water that those interstices have been filled with those materials, water must be, like fire, an universal solvent, or cause of fluidity, and we must change entirely our opinion of water in relation to its chemical character. But there is no necessity thus to violate our chemical principles, in order to explain certain natural appearances; more especially if those appearances may be explained in another manner, consistently with the known laws of nature.

If, again, it is by means of heat and fusion that the loose and porous structure of strata shall be supposed to have been consolidated, then every difficulty which had occurred in reasoning upon the power or agency of water is at once removed. The loose and discontinuous body of a stratum may be closed by means of softness and compression; the porous structure of the materials may be consolidated, in a similar manner, by the fusion of their substance; and foreign matter may be introduced into the open structure of strata, in form of steam or exhalation, as well as in the fluid state of fusion; consequently, heat is an agent competent for the consolidation of strata, which water alone is not. If, therefore, such an agent could be found acting in the natural place of strata, we must p.r.o.nounce it proper to bring about that end.

The examination of nature gives countenance to this supposition, so far as strata are found consolidated by every species of substance, and almost every possible mixture of those different substances; consequently, however difficult it may appear to have this application of heat, for the purpose of consolidating strata formed at the bottom of the ocean, we cannot, from natural appearances, suppose any other cause, as having actually produced the effects which are now examined.

This question, with regard to the means of consolidating the strata of the globe, is, to natural history, of the greatest importance; and it is essential in the theory now proposed to be given of the mineral system.

It would, therefore, require to be discussed with some degree of precision in examining the particulars; but of these, there is so great a field, and the subject is so complicated in its nature, that volumes might be written upon particular branches only, without exhausting what might be laid upon the subject; because the evidence, though strong in many particulars, is chiefly to be enforced by a mult.i.tude of facts, conspiring, in a diversity of ways, to point out one truth, and by the impossibility of reconciling all these facts, except by means of one supposition.

But, as it is necessary to give some proof of that which is to be a principle in our reasoning afterwards, I shall now endeavour to generalise the subject as much as possible, in order to answer that end, and, at the same time, to point out the particular method of inquiry.

There are to be found, among the various strata of the globe, bodies formed of two different kinds of substances, _siliceous_ bodies, and those which may be termed _sulphureous_ or _phlogistic_. With one or other, or both of those we substances, every different consolidated stratum of the globe will be found so intimately mixed, or closely connected, that it must be concluded, by whatever cause those bodies of siliceous and sulphureous matter had been changed from a fluid to a concreted state, the strata must have been similarly affected by the same cause.

These two species of bodies, therefore, the siliceous and the sulphureous, may now be examined, in relation to the causes of their concretion, with a view to determine, what has been the general concreting or consolidating power, which has operated universally in the globe; and particularly to show, it has not been by means of any fluid solution, that strata in general have been consolidated, or that those particular substances have been crystallized and concreted.

Siliceous matter, physically speaking, is not soluble in water; that is to say, in no manner of way have we been enabled to learn, that water has the power of dissolving this matter.

Many other substances, which are so little soluble in water, that their solubility could not be otherwise detected of themselves, are made to appear soluble by means of siliceous matter; such is feld-spar, one of the component parts of rock-granite.

Feld-spar is a compound of siliceous, argillaceous, and calcareous earth, intimately united together. This compound siliceous body being, for ages, exposed to the weather, the calcareous part of it is dissolved, and the siliceous part is left in form of a soft white earth.

But whether this dissolution is performed by pure water, or by means also of an acid, may perhaps be questioned. This, however, is certain, that we must consider siliceous substances as insoluble in water.

The water of Glezer in Iceland undoubtedly contains this substance in solution; but there is no reason to believe, that it is here dissolved by any other than the natural means; that is, an alkaline substance, by which siliceous bodies may be rendered soluble in water[5].

[Note 5: This conjecture, which I had thus formed, has been fully confirmed by the accurate a.n.a.lysis of those waters. See vol. 3d. of the Phil. Trans. of Edin.]

It may be, therefore, a.s.serted, that no siliceous body having the hardness of flint, nor any crystallization of that substance, has ever been formed, except by fusion. If, by any art, this substance shall be dissolved in simple water, or made to crystallise from any solution, in that case, the a.s.sertion which has been here made may be denied.

But where there is not the vestige of any proof, to authorise the supposition of flinty matter being dissolved by water, or crystallized from that solution, such an hypothesis cannot be admitted, in opposition to general and evident appearances[6].

[Note 6: The Chevalier de Dolomieu has imagined an ingenious theory for the solution of siliceous substances in water [Journal de Physique, Mai 1792.]. This theory has not been taken up merely at a venture, but is founded upon very accurate and interesting chemical experiments.

Hitherto, however, the nature of the siliceous substance is not sufficiently known, to enable us to found, upon chemical principles, the mineral operations of nature. That siliceous substance may be dissolved, or rendered soluble in water, by means of alkaline salt, and that it may be also volatilised by means of the fluor acid, is almost all that we know upon the subject. But this is saying no more in relation to the mineral operations employed upon the siliceous substance, than it would be, in relation to those upon gold, to say that this metal is dissolved by aqua regia.

It is to be admitted, that every simple substance may have its menstruum, by means of which it may be retained with water in a dissolved state; but from this it does not follow, that it is by the means of aqueous solutions of all those mineral bodies, that nature operates the consolidation of bodies, which we find actually accomplished with all those different substances. It is the business of this work to show, that from all appearances in the mineral regions, as well as those upon the surface in the atmosphere, the supposition, of that manner of consolidating bodies by solution, is inconsistent both with natural appearances, and also with chemical principles.

Our ingenious author, who has, with, great diligence as well as an enlightened mind, observed the operations of nature upon the surface of the earth, here says, "ce n'est pas sans etonnement que je remarque depuis long-temps que jamais aucune eau qui coule a la surface de la terre n'attaque le quartz, aucune n'en tient en dissolution, pendant que celles qui circulent interieurement le corrodent aussi souvent qu'elles le deposent."--How dangerous it is in science for ingenious men to allow themselves to form conclusions, which the principles on which they reason do not strictly warrant, we have a remarkable example in the present case.

M. de Dolomieu sees no corrosion of quartz, or solution of that substance, upon the surface of the earth; from this, then, he concludes, that siliceous substance is not dissolved in that situation of things.

On the other hand, he finds siliceous bodies variously concreted among the solid strata of the earth; and, from this he concludes, that siliceous substance has been both dissolved by water in the strata, and also there again concreted and crystallised in having been separated from the water. This is certainly what we all perceive; but we do not all allow ourselves to draw such inconclusive inferences from our premises. Notwithstanding the greatest accuracy of our observations, quartz may be dissolvable in a minute degree by water, upon the surface of this earth; and, all the appearances of siliceous bodies, in the mineral regions, where we cannot immediately see the operation, may be better explained by fusion than by aqueous solution.

But, from his chemical experiments, our author has conjectured that there may be a phlogistic substance, by means of which the siliceous earth is dissolved when in darkness; and that this solvent loses its power, if exposed to the light of day. I have one observation to oppose to this ingenious theory. Under deep black mosses, through which no ray of light can penetrate, every condition for dissolving siliceous bodies should be found, according to the supposition in question; neither will sufficient time be found wanting, in those deep mosses, upon the summits of our mountains; yet, examine the matter of fact? not the smallest solution is to be perceived in the siliceous parts of the stones which are found under those mosses, but every particle of iron is dissolved, so that the surface of every stone is white, and nothing but the siliceous earth of the feld-spar, and perhaps the argillaceous, is left.

Here we have in this author an instructive example: No person, in my opinion, has made such enlightened or scientific experiments, or such judicious observations with regard to the nature of siliceous substance, as a compound thing; no person reasons more distinctly in general, or sees more clearly the importance of his principles; yet, with regard to mineral concretions, how often has he been drawn thus inadvertently into improper generalization! I appeal to the a.n.a.logy which, in this treatise, he has formed, between the stalactical concretions upon the surface of the earth, and the mineral concretions of siliceous substance. As an example of the great lights, and penetrating genius, of this a.s.siduous studier of nature, I refer to the judicious observations which he has made upon the subject of aluminous earth, in this dissertation.

I am surprised to find this enlightened naturalist seeking, in the origin of this globe of our earth, a general principle of fluidity or solution in water, like the alkahest of the alchymists, by means of which the different substances in the chemical const.i.tution of precious stones might have been united as well as crystallised. One would have thought, that a philosopher, so conversant in the operations of subterraneous fire, would have perceived, that there is but one general principle of fluidity or dissolution, and that this is heat.]

Besides this proof for the fusion of siliceous bodies, which is indirect, arising from the in dissolubility of that substance in water, there is another, which is more direct, being founded upon appearances which are plainly inconsistent with any other supposition, except that of simple fluidity induced by heat. The proof I mean is, the penetration of many bodies with a flinty substance, which, according to every collateral circ.u.mstance, must have been performed by the flinty matter in a simply fluid state, and not in a state of dissolution by a solvent.

These are flinty bodies perfectly insulated in strata both of chalk and sand. It requires but inspection to be convinced. It is not possible that flinty matter could be conveyed into the middle of those strata, by a menstruum in which it was dissolved, and thus deposited in that place, without the smallest trace of deposition in the surrounding parts.