33. Strange Behavior of Water. One has but to remember that bottles of water burst when they freeze, and that ice floats on water like wood, to know that water expands on freezing or on solidifying. A quant.i.ty of water which occupies 100 cubic feet of s.p.a.ce will, on becoming ice, need 109 cubic feet of s.p.a.ce. On a cold winter night the water sometimes freezes in the water pipes, and the pipes burst. Water is very peculiar in expanding on solidification, because most substances contract on solidifying; gelatin and jelly, for example, contract so much that they shrink from the sides of the dish which contains them.

If water contracted in freezing, ice would be heavier than water and would sink in ponds and lakes as fast as it formed, and our streams and ponds would become ma.s.ses of solid ice, killing all animal and plant life. But the ice is lighter than water and floats on top, and animals in the water beneath are as free to live and swim as they were in the warm sunny days of summer. The most severe winter cannot freeze a deep lake solid, and in the coldest weather a hole made in the ice will show water beneath the surface. Our ice boats cut and break the ice of the river, and through the water beneath our boats daily ply their way to and fro, independent of winter and its blighting blasts.

While most of us are familiar with the bursting of water pipes on a cold night, few of us realize the influence which freezing water exerts on the character of the land around us.

Water sinks into the ground and, on the approach of winter, freezes, expanding about one tenth of its volume; the expanding ice pushes the earth aside, the force in some cases being sufficient to dislodge even huge rocks. In the early days in New England it was said by the farmers that "rocks grew," because fields cleared of stones in the fall became rock covered with the approach of spring; the rocks and stones hidden underground and unseen in the fall were forced to the surface by the winter's expansion. We have all seen fence posts and bricks pushed out of place because of the heaving of the soil beneath them. Often householders must relay their pavements and walks because of the damage done by freezing water.

The most conspicuous effect of the expansive power of freezing water is seen in rocky or mountainous regions (Fig. 21). Water easily finds entrance into the cracks and crevices of the rocks, where it lodges until frozen; then it expands and acts like a wedge, widening cracks, chiseling off edges, and even breaking rocks asunder. In regions where frequent frosts occur, the destructive action of water works constant changes in the appearance of the land; small cracks and crevices are enlarged, ma.s.sive rocks are pried up out of position, huge slabs are split off, and particles large and small are forced from the parent rock. The greater part of the debris and rubbish brought down from the mountain slopes by the spring rains owes its origin to the fact that water expands when it freezes.

[Ill.u.s.tration: FIG. 21.--The destruction caused by freezing water.]

34. Heat Necessary to Dissolve a Substance. It requires heat to dissolve any substance, just as it requires heat to change ice to water. If a handful of common salt is placed in a small cup of water and stirred with a thermometer, the temperature of the mixture falls several degrees. This is just what one would expect, because the heat needed to liquefy the salt must come from somewhere, and naturally it comes from the water, thereby lowering the temperature of the water.

We know very well that potatoes cease boiling if a pinch of salt is put in the water; this is because the temperature of the water has been lowered by the amount of heat necessary to dissolve the salt.

Let some snow or chopped ice be placed in a vessel and mixed with one third its weight of coa.r.s.e salt; if then a small tube of cold water is placed in this mixture, the water in the test tube will soon freeze solid. As soon as the snow and salt are mixed they melt. The heat necessary for this comes in part from the air and in part from the water in the test tube, and the water in the tube becomes in consequence cold enough to freeze. But the salt mixture does not freeze because its freezing point is far below that of pure water. The use of salt and ice in ice-cream freezers is a practical application of this principle. The heat necessary for melting the mixture of salt and ice is taken from the cream which thus becomes cold enough to freeze.

CHAPTER IV

BURNING OR OXIDATION

35. Why Things Burn. The heat of our bodies comes from the food we eat; the heat for cooking and for warming our houses comes from coal.

The production of heat through the burning of coal, or oil, or gas, or wood, is called combustion. Combustion cannot occur without the presence of a substance called oxygen, which exists rather abundantly in the air; that is, one fifth of our atmosphere consists of this substance which we call oxygen. We throw open our windows to allow fresh air to enter, and we take walks in order to breathe the pure air into our lungs. What we need for the energy and warmth of our bodies is the oxygen in the air. Whether we burn gas or wood or coal, the heat which is produced comes from the power which these various substances possess to combine with oxygen. We open the draft of a stove that it may "draw well": that it may secure oxygen for burning.

We throw a blanket over burning material to smother the fire: to keep oxygen away from it. Burning, or oxidation, is combining with oxygen, and the more oxygen you add to a fire, the hotter the fire will burn, and the faster. The effect of oxygen on combustion may be clearly seen by thrusting a smoldering splinter into a jar containing oxygen; the smoldering splinter will instantly flare and blaze, while if it is removed from the jar, it loses its flame and again burns quietly.

Oxygen for this experiment can be produced in the following way.

[Ill.u.s.tration: FIG. 22.--Preparing oxygen from pota.s.sium chlorate and manganese dioxide.]

36. How to Prepare Oxygen. Mix a small quant.i.ty of pota.s.sium chlorate with an equal amount of manganese dioxide and place the mixture in a strong test tube. Close the mouth of the tube with a one-hole rubber stopper in which is fitted a long, narrow tube, and clamp the test tube to an iron support, as shown in Figure 22. Fill the trough with water until the shelf is just covered and allow the end of the delivery tube to rest just beneath the hole in the shelf.

Fill a medium-sized bottle with water, cover it with a gla.s.s plate, invert the bottle in the trough, and then remove the gla.s.s plate. Heat the test tube very gently, and when gas bubbles out of the tube, slip the bottle over the opening in the shelf, so that the tube runs into the bottle. The gas will force out the water and will finally fill the bottle. When all the water has been forced out, slip the gla.s.s plate under the mouth of the bottle and remove the bottle from the trough.

The gas in the bottle is oxygen.

Everywhere in a large city or in a small village, smoke is seen, indicating the presence of fire; hence there must exist a large supply of oxygen to keep all the fires alive. The supply of oxygen needed for the fires of the world comes largely from the atmosphere.

37. Matches. The burning material is ordinarily set on fire by matches, thin strips of wood tipped with sulphur or phosphorus, or both. Phosphorus can unite with oxygen at a fairly low temperature, and if phosphorus is rubbed against a rough surface, the friction produced will raise the temperature of the phosphorus to a point where it can combine with oxygen. The burning phosphorus kindles the wood of the match, and from the burning match the fire is kindled. If you want to convince yourself that friction produces heat, rub a cent vigorously against your coat and note that the cent becomes warm.

Matches have been in use less than a hundred years. Primitive man kindled his camp fire by rubbing pieces of dry wood together until they took fire, and this method is said to be used among some isolated distant tribes at the present time. A later and easier way was to strike flint and steel together and to catch the spark thus produced on tinder or dry fungus. Within the memory of some persons now living, the tinder box was a valuable a.s.set to the home, particularly in the pioneer regions of the West.

38. Safety Matches. Ordinary phosphorus, while excellent as a fire-producing material, is dangerously poisonous, and those to whom the dipping of wooden strips into phosphorus is a daily occupation suffer with a terrible disease which usually attacks the teeth and bones of the jaw. The teeth rot and fall out, abscesses form, and bones and flesh begin to decay; the only way to prevent the spread of the disease is to remove the affected bone, and in some instances it has been necessary to remove the entire jaw. Then, too, matches made of yellow or white phosphorus ignite easily, and, when rubbed against any rough surface, are apt to take fire. Many destructive fires have been started by the accidental friction of such matches against rough surfaces.

For these reasons the introduction of the so-called safety match was an important event. When common phosphorus, in the dangerous and easily ignited form, is heated in a closed vessel to about 250 C., it gradually changes to a harmless red ma.s.s. The red phosphorus is not only harmless, but it is difficult to ignite, and, in order to be ignited by friction, must be rubbed on a surface rich in oxygen. The head of a safety match is coated with a mixture of glue and oxygen-containing compounds; the surface on which the match is to be rubbed is coated with a mixture of red phosphorus and glue, to which finely powdered gla.s.s is sometimes added in order to increase the friction. Unless the head of the match is rubbed on the prepared phosphorus coating, ignition does not occur, and accidental fires are avoided.

Various kinds of safety matches have been manufactured in the last few years, but they are somewhat more expensive than the ordinary form, and hence manufacturers are reluctant to subst.i.tute them for the cheaper matches. Some foreign countries, such as Switzerland, prohibit the sale of the dangerous type, and it is hoped that the United States will soon follow the lead of these countries in demanding the sale of safety matches only.

39. Some Unfamiliar Forms of Burning. While most of us think of burning as a process in which flames and smoke occur, there are in reality many modes of burning accompanied by neither flame nor smoke.

Iron, for example, burns when it rusts, because it slowly combines with the oxygen of the air and is transformed into new substances.

When the air is dry, iron does not unite with oxygen, but when moisture is present in the air, the iron unites with the oxygen and turns into iron rust. The burning is slow and unaccompanied by the fire and smoke so familiar to us, but the process is none the less burning, or combination with oxygen. Burning which is not accompanied by any of the appearances of ordinary burning is known as oxidation.

The tendency of iron to rust lessens its efficiency and value, and many devices have been introduced to prevent rusting. A coating of paint or varnish is sometimes applied to iron in order to prevent contact with air. The galvanizing of iron is another attempt to secure the same result; in this process iron is dipped into molten zinc, thereby acquiring a coating of zinc, and forming what is known as galvanized iron. Zinc does not combine with oxygen under ordinary circ.u.mstances, and hence galvanized iron is immune from rust.

Decay is a process of oxidation; the tree which rots slowly away is undergoing oxidation, and the result of the slow burning is the decomposed matter which we see and the invisible gases which pa.s.s into the atmosphere. The log which blazes on our hearth gives out sufficient heat to warm us; the log which decays in the forest gives out an equivalent amount of heat, but the heat is evolved so slowly that we are not conscious of it. Burning accompanied by a blaze and intense heat is a rapid process; burning unaccompanied by fire and appreciable heat is a slow, gradual process, requiring days, weeks, and even long years for its completion.

Another form of oxidation occurs daily in the human body. In Section 35 we saw that the human body is an engine whose fuel is food; the burning of that food in the body furnishes the heat necessary for bodily warmth and the energy required for thought and action. Oxygen is essential to burning, and the food fires within the body are kept alive by the oxygen taken into the body at every breath by the lungs.

We see now one reason for an abundance of fresh air in daily life.

40. How to Breathe. Air, which is essential to life and health, should enter the body through the nose and _not through the mouth_.

The peculiar nature and arrangement of the membranes of the nose enable the nostrils to clean, and warm, and moisten the air which pa.s.ses through them to the lungs. Floating around in the atmosphere are dust particles which ought not to get into the lungs. The nose is provided with small hairs and a moist inner membrane which serve as filters in removing solid particles from the air, and in thus purifying it before its entrance into the lungs.

In the immediate neighborhood of three Philadelphia high schools, having an approximate enrollment of over 8000 pupils, is a huge manufacturing plant which day and night pours forth grimy smoke and soot into the atmosphere which must supply oxygen to this vast group of young lives. If the vital importance of nose breathing is impressed upon these young people, the harmful effect of the foul air may be greatly lessened, the smoke particles and germs being held back by the nose filters and never reaching the lungs. If, however, this principle of hygiene is not brought to their attention, the dangerous habit of breathing through the open, or at least partially open, mouth will continue, and objectionable matter will pa.s.s through the mouth and find a lodging place in the lungs.

There is another very important reason why nose breathing is preferable to mouth breathing. The temperature of the human body is approximately 98 F., and the air which enters the lungs should not be far below this temperature. If air reaches the lungs through the nose, its journey is relatively long and slow, and there is opportunity for it to be warmed before it reaches the lungs. If, on the other hand, air pa.s.ses to the lungs by way of the mouth, the warming process is brief and insufficient, and the lungs suffer in consequence.

Naturally, the gravest danger is in winter.

41. Cause of Mouth Breathing. Some people find it difficult to breathe through the nostrils on account of growths, called adenoids, in the nose. If you have a tendency toward mouth breathing, let a physician examine your nose and throat.

Adenoids not only obstruct breathing and weaken the whole system through lack of adequate air, but they also press upon the blood vessels and nerves of the head and interfere with normal brain development. Moreover, they interfere in many cases with the hearing, and in general hinder activity and growth. The removal of adenoids is simple, and carries with it only temporary pain and no danger. Some physicians claim that the growths disappear in later years, but even if that is true, the physical and mental development of earlier years is lost, and the person is backward in the struggle for life and achievement.

[Ill.u.s.tration: FIG. 23.--Intelligent expression is often lacking in children with adenoid growths.]

42. How to Build a Fire. Substances differ greatly as to the ease with which they may be made to burn or, in technical terms, with which they may be made to unite with oxygen. For this reason, we put light materials, like shavings, chips, and paper, on the grate, twisting the latter and arranging it so that air (oxygen in the air) can reach a large surface; upon this we place small sticks of wood, piling them across each other so as to allow entrance for the oxygen; and finally upon this we place our hard wood or coal.

The coal and the large sticks cannot be kindled with a match, but the paper and shavings can, and these in burning will heat the large sticks until they take fire and in turn kindle the coal.

43. Spontaneous Combustion. We often hear of fires "starting themselves," and sometimes the statement is true. If a pile of oily rags is allowed to stand for a time, the oily matter will begin to combine slowly with oxygen and as a result will give off heat. The heat thus given off is at first insufficient to kindle a fire; but as the heat is retained and acc.u.mulated, the temperature rises, and finally the kindling point is reached and the whole ma.s.s bursts into flames. For safety's sake, all oily cloths should be burned or kept in metal vessels.

44. The Treatment of Burns. In spite of great caution, burns from fires, steam, or hot water do sometimes occur, and it is well to know how to relieve the suffering caused by them and how to treat the injury in order to insure rapid healing.

Burns are dangerous because they destroy skin and thus open up an entrance into the body for disease germs, and in addition because they lay bare nerve tissue which thereby becomes irritated and causes a shock to the entire system.

In mild burns, where the skin is not broken but is merely reddened, an application of moist baking soda brings immediate relief. If this substance is not available, flour paste, lard, sweet oil, or vaseline may be used.

In more severe burns, where blisters are formed, the blisters should be punctured with a sharp, sterilized needle and allowed to discharge their watery contents before the above remedies are applied.

In burns severe enough to destroy the skin, disinfection of the open wound with weak carbolic acid or hydrogen peroxide is very necessary.

After this has been done, a soft cloth soaked in a solution of linseed oil and limewater should be applied and the whole bandaged. In such a case, it is important not to use cotton batting, since this sticks to the rough surface and causes pain when removed.

45. Carbon Dioxide. _A Product of Burning._ When any fuel, such as coal, gas, oil, or wood, burns, it sends forth gases into the surrounding atmosphere. These gases, like air, are invisible, and were unknown to us for a long time. The chief gas formed by a burning substance is called carbon dioxide (CO_2) because it is composed of one part of carbon and two parts of oxygen. This gas has the distinction of being the most widely distributed gaseous compound of the entire world; it is found in the ocean depths and on the mountain heights, in brilliantly lighted rooms, and most abundantly in manufacturing towns where factory chimneys constantly pour forth hot gases and smoke.

Wood and coal, and in fact all animal and vegetable matter, contain carbon, and when these substances burn or decay, the carbon in them unites with oxygen and forms carbon dioxide.

The food which we eat is either animal or vegetable, and it is made ready for bodily use by a slow process of burning within the body; carbon dioxide accompanies this bodily burning of food just as it accompanies the fires with which we are more familiar. The carbon dioxide thus produced within the body escapes into the atmosphere with the breath.

We see that the source of carbon dioxide is practically inexhaustible, coming as it does from every stove, furnace, and candle, and further with every breath of a living organism.

46. Danger of Carbon Dioxide. When carbon dioxide occurs in large quant.i.ties, it is dangerous to health, because it interferes with normal breathing, lessening the escape of waste matter through the breath and preventing the access to the lungs of the oxygen necessary for life. Carbon dioxide is not poisonous, but it cuts off the supply of oxygen, just as water cuts it off from a drowning man.