See _Lives of the Queens of England_, by A. Strickland, iii. (1851); _The Wives of Henry VIII_., by M. Hume (1905); _Henry VIII_., by A.F.

Pollard (1905); _Four Original Doc.u.ments relating to the Marriage of Henry VIII. to Anne of Cleves_, ed. by E. and G. Goldsmid (1886); for the pseudo Anne of Cleves see _Allgemeine deutsche Biographie_, i.

467. (P. C. Y.)

ANNE OF DENMARK (1574-1619), queen of James I. of England and VI. of Scotland, daughter of King Frederick II. of Denmark and Norway and of Sophia, daughter of Ulric III., duke of Mecklenburg, was born on the 12th of December 1574. On the 20th of August 1589, in spite of Queen Elizabeth's opposition, she was married by proxy to King James, without dower, the alliance, however, settling definitely the Scottish claims to the Orkney and Shetland Islands. Her voyage to Scotland was interrupted by a violent storm--for the raising of which several Danish and Scottish witches were burned or executed--which drove her on the coast of Norway, whither the impatient James came to meet her, the marriage taking place at Opslo (now Christiania) on the 23rd of November. The royal couple, after visiting Denmark, arrived in Scotland in May 1590. The position of queen consort to a Scottish king was a difficult and perilous one, and Anne was attacked in connexion with various scandals and deeds of violence, her share in which, however, is supported by no evidence. The birth of an heir to the throne (Prince Henry) in 1504 strengthened her position and influence; but the young prince, much to her indignation, was immediately withdrawn from her care and entrusted to the keeping of the earl and countess of Mar at Stirling Castle; in 1595 James gave a written command, forbidding them in case of his death to give up the prince to the queen till he reached the age of eighteen. The king's intention was, no doubt, to secure himself and the prince against the unruly n.o.bles, though the queen's Roman Catholic tendencies were probably another reason for his decision. Brought up a Lutheran, and fond of pleasure, she had shown no liking for Scottish Calvinism, and soon incurred rebukes on account of her religion, "vanity," absence from church, "night waking and balling." She had become secretly inclined to Roman Catholicism, and attended ma.s.s with the king's connivance. On the death of Queen Elizabeth, on the 24th of March 1603, James preceded her to London. Anne took advantage of his absence to demand possession of the prince, 'and, on the "flat refusal" of the countess of Mar, fell into a pa.s.sion, the violence of which occasioned a miscarriage and endangered her life. In June she followed the king to England (after distributing all her effects in Edinburgh among her ladies) with the prince and the coffin containing the body of her dead infant, and reached Windsor on the 2nd of July, where amidst other forms of good fortune she entered into the possession of Queen Elizabeth's 6000 dresses.

On the 24th of July Anne was crowned with the king, when her refusal to take the sacrament according to the Anglican use created some sensation.

She communicated on one occasion subsequently and attended Anglican service occasionally; but she received consecrated objects from Pope Clement VIII., continued to hear ma.s.s, and, according to Galluzzi, supported the schemes for the conversion of the prince of Wales and of England, and for the prince's marriage with a Roman Catholic princess, which collapsed on his death in 1612. She was claimed as a convert by the Jesuits.[1] Nevertheless on her deathbed, when she was attended by the archbishop of Canterbury and the bishop of London, she used expressions which were construed as a declaration of Protestantism.

Notwithstanding religious differences she lived in great harmony and affection with the king, latterly, however, residing mostly apart. She helped to raise Buckingham to power in the place of Somerset, maintained friendly relations with him, and approved of his guidance and control of the king. In spite of her birth and family she was at first favourably inclined to Spain, disapproved of her daughter Elizabeth's marriage with the elector palatine, and supported the Spanish marriages for her sons, but subsequently veered round towards France. She used all her influence in favour of the unfortunate Raleigh, answering his pet.i.tion to her for protection with a personal letter of appeal to Buckingham to save his life. "She carrieth no sway in state matters," however, it was said of her in 1605, "and, _praeter rem uxoriam_, hath no great reach in other affairs." "She does not mix herself up in affairs, though the king tells her anything she chooses to ask, and loves and esteems her."[2] Her interest in state matters was only occasional, and secondary to the pre-occupations of court festivities, masks, progresses, dresses, jewels, which she much enjoyed; the court being, says Wilson--whose severity cannot entirely suppress his admiration--"a continued maskarado, where she and her ladies, like so many nymphs or Nereides, appeared ... to the ravishment of the beholders," and "made the night more glorious than the day." Occasionally she even joined in the king's sports, though here her only recorded exploit was her accidental shooting of James's "most princ.i.p.al and special hound," Jewel. Her extravagant expenditure, returned by Salisbury in 1605 at more than 50,000 and by Chamberlain at her death at more than 84,000, was unfavourably contrasted with the economy of Queen Elizabeth; in spite of large allowances and grants of estates which included Oatlands, Greenwich House and Nonsuch, it greatly exceeded her income, her debts in 1616 being reckoned at nearly 10,000, while her jewelry and her plate were valued at her death at nearly half a million. Anne died after a long illness on the 2nd of March 1619, and was buried in Westminster Abbey. She was generally regretted. The severe Wilson, while rebuking her gaieties, allows that she was "a good woman," and that her character would stand the most prying investigation. She was intelligent and tactful, a faithful wife, a devoted mother and a staunch friend. Besides several children who died in infancy she had Henry, prince of Wales, who died in 1612, Charles, afterwards King Charles I., and Elizabeth, electress palatine and queen of Bohemia.

BIBLIOGRAPHY.--See Dr A.W. Ward's article in the _Dict, of Nat.

Biography_, with authorities; _Lives of the Queens of England_, by A.

Strickland (1844), vii.; "Life and Reign of King James I.," by A.

Wilson, in _History of England_ (1706); _Istoria del Granducato di Toscana_, by R. Galluzzi (1781), lib. vi. cap. ii.; _Cal. of State Papers--Domestic and Venetian_; _Hist. MSS. Comm. Series, MSS, of Marq. of Salisbury_, iii. 420, 438, 454, ix. 54; _Harleian MSS._ 5176, art. 22, 293, art. 106. Also see bibliography to the article on JAMES I. (P. C. Y.)

FOOTNOTES:

[1] _Fasti S. J._, by P. Joannis Drews (pub. 1723), p. 160.

[2] _Cal. of St. Pap.--Venetian_, x. 513.

ANNE OF FRANCE (1460-1522), dame de Beaujeu, was the eldest daughter of Louis XI. and Charlotte of Savoy. Louis XI. betrothed her at first to Nicholas of Anjou, and afterwards offered her hand successively to Charles the Bold, to the duke of Brittany, and even to his own brother, Charles of France. Finally she married Pierre de Beaujeu, a younger brother of the duke of Bourbon. Before his death Louis XI. entrusted to Pierre de Beaujeu and Anne the entire charge of his son, Charles VIII., a lad of thirteen; and from 1483 to 1492 the Beaujeus exercised a virtual regency. Anne was a true daughter of Louis XI. Energetic, obstinate, cunning and unscrupulous, she inherited, too, her father's avarice and rapacity. Although they made some concessions, the Beaujeus succeeded in maintaining the results of the previous reign, and in triumphing over the feudal intrigues and coalitions, as was seen from the meeting of the estates general in 1484, and the results of the "Mad War" (1485) and the war with Brittany (1488); and in spite of the efforts of Maximilian of Austria they concluded the marriage of Charles VIII. and Anne, d.u.c.h.ess of Brittany (1491). But a short time afterwards the king disengaged himself completely from their tutelage, to the great detriment of the kingdom. In 1488 Pierre de Beaujeu had succeeded to the Bourbonnais, the last great fief of France. He died in 1503, but Anne survived him twenty years. From her establishments at Moulins and Chantelle in the Bourbonnais she continued henceforth vigorously to defend the Bourbon cause against the royal family. Anne's only daughter, Suzanne, had married in 1505 her cousin, Charles of Bourbon, count of Montpensier, the future constable; and the question of the succession of Suzanne, who died in 1521, was the determining factor of the treason of the constable de Bourbon (1523). Anne had died some months before, on the 14th of November 1522.

See P. Pelicier, _Essai sur le gouvernement de la Dame de Beaujeu_ (Chartres, 1882). (J. I.)

ANNEALING, HARDENING AND TEMPERING. Annealing (from the prefix _an_, and the old English _aelan_, to burn or bake; the meaning has probably also been modified from the French _nieler_, to enamel black on gold or silver, from the med. Lat. _nigellare_, to make black; cf. _niello_) is a process of treating a metal or alloy by heat with the object of imparting to it a certain condition of ductility, extensibility, or a certain grade of softness or hardness, with all that is involved in and follows from those conditions. The effect may be mechanical only, or a chemical change may take place also. Sometimes the causes are obvious, in other cases they are more or less obscure. But of the actual facts, and the immense importance of this operation as well as of the related ones of tempering and hardening in shop processes, there is no question.

When the treatment is of a mechanical character only, there can be no reasonable doubt that the common belief is correct, namely, that the metallic crystals or fibres undergo a molecular rearrangement of some kind. When it is of a chemical character, the process is one of cementation, due to the occlusion of gases in the molecules of the metals.

Numerous examples of annealing due to molecular rearrangement might be selected from the extensive range of workshop operations. The following are a few only:--when a boiler-maker bends the edges of a plate of steel or iron by hammer blows (flanging), he does so in successive stages (heats), at each of which the plate has to be reheated, with inevitable cooling down during the time work is being done upon it. The result is that the plate becomes brittle over the parts which have been subjected to this treatment; and this brittleness is not uniformly distributed, but is localized, and is a source of weakness, inducing a liability to crack. If, however, the plate when finished is raised to a full red heat, and allowed to cool down away from access of cool air, as in a furnace, or underneath wood ashes, it resumes its old ductility. The plate has been annealed, and is as safe as it was before it was f.l.a.n.g.ed.

Again, when a sheet of thin metal is forced to a.s.sume a shape very widely different from its original plane aspect, as by hammering, or by drawing out in a press--a cartridge case being a familiar example--it is necessary to anneal it several times during the progress of the operation. Without such annealing it would never arrive at the final stage desired, but would become torn asunder by the extension of its metallic fibres. Cutting tools are made of steel having sufficient carbon to afford capacity for hardening. Before the process is performed, the condition in which the carbon is present renders the steel so hard and tough as to render the preliminary turning or shaping necessary in many cases (e.g. in milling cutters) a tedious operation.

To lessen this labour, the steel is first annealed. In this case it is brought to a low red heat, and allowed to cool away from the air. It can then be machined with comparative ease and be subsequently hardened or tempered. When a metallic structure has endured long service a state of fatigue results. Annealing is, where practicable, resorted to in order to restore the original strength. A familiar ill.u.s.tration is that of chains which are specially liable to succ.u.mb to constant overstrain if continued for only a year or two. This is so well known that the practice is regularly adopted of annealing the chains at regular intervals. They are put into a clear hot furnace and raised to a low red heat, continued for a few hours, and then allowed to cool down in the furnace after the withdrawal of the source of heat. Before the annealing the fracture of a link would be more crystalline than afterwards.

In these examples, and others of which these are typical, two conditions are essential, one being the grade of temperature, the other the cooling. The temperature must never be so high as to cause the metal to become overheated, with risk of burning, nor so low as to prevent the penetration of the substance with a good volume of heat. It must also be continued for sufficient time. More than this cannot be said. Each particular piece of work requires its own treatment and period, and nothing but experience of similar work will help the craftsman. The cooling must always be gradual, such as that which results from removing the source of heat, as by drawing a furnace fire, or covering with non-conducting substances.

The chemical kind of annealing is specifically that employed in the manufacture of malleable cast iron. In this process, castings are made of white iron,--a brittle quality which has its carbon wholly in the combined state. These castings, when subjected to heat for a period of ten days or a fortnight, in closed boxes, in the presence of substances containing oxygen, become highly ductile. This change is due to the absorption of the carbon by the oxygen in the cementing material, a comparatively pure soft iron being left behind. The result is that the originally hard, brittle castings after this treatment may be cut with a knife, and be bent double and twisted into spirals without fracturing.

The distinction between _hardening_ and _tempering_ is one of degree only, and both are of an opposite character to annealing. Hardening, in the shop sense, signifies the making of a piece of steel about as hard as it can be made--"gla.s.s hard"--while tempering indicates some stage in an infinite range between the fully hardened and the annealed or softened condition. As a matter of convenience only, hardening is usually a stage in the work of tempering. It is easier to harden first, and "let down" to the temper required, than to secure the exact heat for tempering by raising the material to it. This is partly due to the long established practice of estimating temperature by colour tints; but this is being rapidly invaded by new methods in which the temper heat is obtained in furnaces provided with pyrometers, by means of which exact heat regulation is readily secured, and in which the heating up is done gradually. Such furnaces are used for hardening b.a.l.l.s for bearings, cams, small toothed wheels and similar work, as well as for tempering springs, milling cutters and other kinds of cutting tools. But for the cutting tools having single edges, as used in engineers' shops, the colour test is still generally retained.

In the practice of hardening and tempering tools by colour, experience is the only safe guide. Colour tints vary with degrees of light; steels of different brands require different treatment in regard to temperature and quenching; and steels even of identical chemical composition do not always behave alike when tempered. Every fresh brand of steel has, therefore, to be treated at first in a tentative and experimental fashion in order to secure the best possible results. The larger the ma.s.ses of steel, and the greater the disparity in dimensions of adjacent parts, the greater is the risk of cracking and distortion. Excessive length and the presence of keen angles increase the difficulties of hardening. The following points have to be observed in the work of hardening and tempering.

A grade of steel must be selected of suitable quality for the purpose for which it has to be used. There are a number of such grades, ranging from about 1 to % content of carbon, and each having its special utility. Overheating must be avoided, as that burns the steel and injures or ruins it. A safe rule is never to heat any grade of steel to a temperature higher than that at which experience proves it will take the temper required. Heating must be regular and thorough throughout, and must therefore be slowly done when dealing with thick ma.s.ses.

Contact with sulphurous fuel must be avoided. Baths of molten alloys of lead and tin are used when very exact temperatures are required, and when articles have thick and thin parts adjacent. But the gas furnaces have the same advantages in a more handy form. Quenching is done in water, oil, or in various hardening mixtures, and sometimes in solids.

Rain water is the princ.i.p.al hardening agent, but various saline compounds are often added to intensify its action. Water that has been long in use is preferred to fresh. Water is generally used cold, but in many cases it is warmed to about 80 F., as for milling cutters and taps, warmed water being less liable to crack the cutters than cold. Oil is preferred to water for small springs, for guns and for many cutters.

Mercury hardens most intensely, because it does not evaporate, and so does lead or wax for the same reason; water evaporates, and in the spheroidal state, as steam, leaves contact with the steel. This is the reason why long and large objects are moved vertically about in the water during quenching, to bring them into contact with fresh cold water.

There is a good deal of mystery affected by many of the hardeners, who are very particular about the composition of their baths, various oils and salts being used in an infinity of combinations. Many of these are the result of long and successful experience, some are of the nature of "fads." A change of bath may involve injury to the steel. The most difficult articles to harden are springs, milling cutters, taps, reamers. It would be easy to give scores of hardening compositions.

Hardening is performed the more efficiently the more rapidly the quenching is done. In the case of thick objects, however, especially milling cutters, there is risk of cracking, due to the difference of temperature on the outside and in the central body of metal. Rapid hardening is impracticable in such objects. This is the cause of the distortion of long taps and reamers, and of their cracking, and explains why their teeth are often protected with soft soap and other substances.

The presence of the body of heat in a tool is taken advantage of in the work of tempering. The tool, say a chisel, is dipped, a length of 2 in.

or more being thus hardened and blackened. It is then removed, and a small area rubbed rapidly with a bit of grindstone, observations being made of the changing tints which gradually appear as the heat is communicated from the hot shank to the cooled end. The heat becomes equalized, and at the same time the approximate temperature for quenching for temper is estimated by the appearance of a certain tint; at that instant the article is plunged and allowed to remain until quite cold. For every different cla.s.s of tool a different tint is required.

"Blazing off" is a particular method of hardening applied to small springs. The springs are heated and plunged in oils, fats, or tallow, which is burned off previous to cooling in air, or in the ashes of the forge, or in oil, or water usually. They are hardened, reheated and tempered, and the tempering by blazing off is repeated for heavy springs. The practice varies almost infinitely with dimensions, quality of steel, and purpose to which the springs have to be applied.

The range of temper for most cutting tools lies between a pale straw or yellow, and a light purple or plum colour. The corresponding range of temperatures is about 430 F. to 530 F., respectively. "Spring temper"

is higher, from dark purple to blue, or 550 F. to 630 F. In many fine tools the range of temperature possible between good and poor results lies within from 5 to 10 F.

There is another kind of hardening which is of a superficial character only--"case hardening." It is employed in cases where toughness has to be combined with durability of surface. It is a cementation process, practised on wrought iron and mild steel, and applied to the link motions of engines, to many pins and studs, eyes of levers, &c. The articles are hermetically luted in an iron box, packed with nitrogenous and saline substances such as potash, bone dust, leather cuttings, and salt. The box is placed in a furnace, and allowed to remain for periods of from twelve to thirty-six hours, during which period the surface of the metal, to a depth of 1/32 to 1/16 in., is penetrated by the cementing materials, and converted into steel. The work is then thrown into water and quenched.

[Ill.u.s.tration: FIG. 1.--Automatic Oil m.u.f.fle Furnace.]

A m.u.f.fle furnace, employed for annealing, hardening and tempering is shown in fig. 1; the heat being obtained by means of petroleum, which is contained in the tank A, and is kept under pressure by pumping at intervals with the wooden handle, so that when the valve B is opened the oil is vaporized by pa.s.sing through a heating coil at the furnace entrance, and when ignited burns fiercely as a gas flame. This pa.s.ses into the furnace through the two holes, C, C, and plays under and up around the m.u.f.fle D, standing on a fireclay slab. The doorway is closed by two fireclay blocks at E. A temperature of over 2000 F. can be obtained in furnaces of this cla.s.s, and the heat is of course under perfect control.

[Ill.u.s.tration: FIG. 2.--Reverbatory Furnace.]

A reverberatory type of gas furnace, shown in fig. 2, differs from the oil furnace in having the flames brought down through the roof, by pipes A, A, A, playing on work laid on the fireclay slab B, thence pa.s.sing under this and out through the elbow-pipe C. The hinged doors, D, give a full opening to the interior of the furnace. It will be noticed in both these furnaces (by Messrs Fletcher, Russell & Co., Ltd.) that the iron casing is a mere sh.e.l.l, enclosing very thick firebrick linings, to retain the heat effectively. (J. G. H.)

ANNECY, the chief town of the department of Haute Savoie in France. Pop.

(1906) 10,763. It is situated at a height of 1470 ft., at the northern end of the lake of Annecy, and is 25 m. by rail N.E. of Aix les Bains.

The surrounding country presents many scenes of beauty. The town itself is a pleasant residence, and contains a 16th century cathedral church, an 18th century bishop's palace, a 14th-16th century castle (formerly the residence of the counts of the Genevois), and the reconstructed convent of the Visitation, wherein now reposes the body of St Francois de Sales (born at the castle of Sales, close by, in 1567; died at Lyons in 1622), who held the see from 1602 to 1622. There is also a public library, with 20,000 volumes, and various scientific collections, and a public garden, with a statue of the chemist Berthollet (1748-1822), who was born not far off. The bishop's see of Geneva was transferred hither in 1535, after the Reformation, but suppressed in 1801, though revived in 1822. There are factories of linen and cotton goods, and of felt hats, paper mills, and a celebrated bell foundry at Annecy le Vieux.

This last-named place existed in Roman times. Annecy itself was in the 10th century the capital of the counts of the Genevois, from whom it pa.s.sed in 1401 to the counts of Savoy, and became French in 1860 on the annexation of Savoy.

The LAKE OF ANNECY is about 9 m. in length by 2 m. in breadth, its surface being 1465 ft. above the level of the sea. It discharges its waters, by means of the Thioux ca.n.a.l, into the Fier, a tributary of the Rhone. (W. A. B. C.)

ANNELIDA, a name derived from J.B.P. Lamarck's term _Annelides_, now used to denote a major phylum or division of coelomate invertebrate animals. Annelids are segmented worms, and differ from the Arthropoda (q.v.), which they closely resemble in many respects, by the possession of a portion of the coelom traversed by the alimentary ca.n.a.l. In the latter respect, and in the fact that they frequently develop by a metamorphosis, they approach the Mollusca (q.v.), but they differ from that group notably in the occurrence of metameric segmentation affecting many of the systems of organs. The body-wall is highly muscular and, except in a few probably specialized cases, possesses chitinous spines, the setae, which are secreted by the ectoderm and are embedded in pits of the skin. They possess a modified anterior end, frequently with special sense organs, forming a head, a segmented nervous system, consisting of a pair of anterior, dorsally-placed ganglia, a ring surrounding the alimentary ca.n.a.l, and a double ventral ganglionated chain, a definite vascular system, an excretory system consisting of nephridia, and paired generative organs formed from the coelomic epithelium. They are divided as follows: (1) Haplodrili (q.v.) or Archiannelida; (2) Chaetopoda (q.v.); (3) Myzostomida (q.v.), probably degenerate Polychaeta; (4) Hirudinea (see CHAETOPODA and LEECH); (5) Echiuroidea (q.v.). (P. C. M.)

ANNET, PETER (1693-1769), English deist, is said to have been born at Liverpool. A schoolmaster by profession, he became prominent owing to his attacks on orthodox theologians, and his membership of a semi-theological debating society, the Robin Hood Society, which met at the "Robin Hood and Little John" in Butcher Row. To him has been attributed a work called _A History of the Man after G.o.d's own Heart_ (1761), intended to show that George II. was insulted by a current comparison with David. The book is said to have inspired Voltaire's _Saul_. It is also attributed to one John Noorthouck (Noorthook). In 1763 he was condemned for blasphemous libel in his paper called the _Free Enquirer_ (nine numbers only). After his release he kept a small school in Lambeth, one of his pupils being James Stephen (1758-1832), who became master in Chancery. Annet died on the 18th of January 1769.

He stands between the earlier philosophic deists and the later propagandists of Paine's school, and "seems to have been the first freethought lecturer" (J.M. Robertson); his essays (_A Collection of the Tracts of a certain Free Enquirer_, 1739-1745) are forcible but lack refinement. He invented a system of shorthand (2nd ed., with a copy of verses by Joseph Priestley).